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Influence of Ar/N2 Flow Rate on Structure and Property for TaN/NbN Multilayered Coatings

Xuehua ZHANG , Yuanbin KANG , Sipeng LIU , Qiang LI , Ying YANG

材料科学技术(英)

TaN/NbN multilayered coatings with nanoscale bilayer periods were synthesized at different Ar/N2 flow rate by r.f. magnetron sputtering. XRD and nano indenter were employed to investigate the influence of Ar/N2 flow rate on microstructure and mechanical properties of the coatings. The low-angle XRD pattern indicated a well-defined composition modulation and layer structure of the multilayered coating. All multilayered coatings almost revealed higher hardness than the rule-of-mixtures value of monolithic TaN and NbN coatings. At FAr:FN2 =10, the multilayered coating possessed excellent hardness, elastic modulus, internal stress, and fracture resistance, compared with ones synthesized at other Ar/N2 flow rates. The layered structure with strong mixture of TaN (110), (111), (200) and Nb2N (101) textures should be related to the enhanced mechanical properties.

关键词: RF magnetron sputtering , TaN/NbN多层膜 , 纳米尺度

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